Sunday, September 18, 2011

Chemistry - 6 Important Events That Led to the Discovery of Quantum Mechanics

Quantum Mechanics is a purely mathematical description of the atom and the subatomic particles. But, that doesn't mean you have to be a nuclear physicist to understand how the atom is arranged or its importance. You can develop an appreciation and a basic understanding of the quantum atom by learning the major events that led to the discovery of the quantum atom.

#1 Discovery of the Electron

In 1898 J.J. Thomson proved the existence of the electron and changed our perception of matter forever. Although others (George Stoney) had predicted there were particles smaller than the atom, they were unable to prove it. J.J. Thomson not only proved the existence of a subatomic particle; he suggested a new atomic model, the "Plum Pudding Model".

#2 Discovery of the Nucleus and Proton

The discovery of the electron led others to test ideas that there might be other subatomic particles. One such person, a former student of J.J. Thomson's, was Ernest Rutherford. Rutherford assigned two assistants, Hans Geiger and Ernest Marsden, to perform the now famous "Gold-foil Experiment". The result of this experiment led Rutherford to conclude that the atom must be mostly space with the majority of its mass located in a very small, dense, centrally located region of the atom. Rutherford named this dense, positively charged region the nucleus later determined that the positive charge was due to another subatomic particle he named the proton.

#3 The Elements' Spectra

An earlier discovery, by Robert Bunsen and Gustav Kirchhoff, that was very important to the development of the Quantum Theory was the discovery of elemental spectra. It was discovered that each element had its own unique emission spectrum that could be used like a fingerprint to identify the element. Later, the quantum theory would provide the explanation for the spectral lines.

#4 The Quantum Theory

Max Planck developed an idea from the observation of black-body radiation that was originally based on a guess that electromagnetic energy could only be emitted in quantized amounts. In other words, the energy could only be used in whole number packets Planck called quanta. This idea became known has "Planck's Postulate" and eventually gave birth to quantum mechanics.

#5 The Photoelectric Effect

In 1905, Albert Einstein published four scientific papers that were to become his greatest works. One of these papers was his explanation of the photoelectric effect. The photoelectric effect is a phenomenon observed when electrons are emitted from matter exposed to beams of light with short wavelengths. In his explanation, Einstein suggested that light contained discrete quanta (photons) rather than continuous waves and the energy in these quanta caused light to behave more like a particle, thus moving the electrons.

Probably the most important part of this discovery was Einstein's use of Planck's constant and Planck's equation in his explanation of the photoelectric effect. This action alone helped expand the quantum theory towards quantum mechanics.

#6 Matter Waves

Probably one of the most astounding scientific discoveries was the de Broglie hypothesis. First proposed as part of Louis de Broglie's doctoral thesis, it stated that if light waves could possess properties then electrons should have wave properties. De Broglie had no empirical evidence whatsoever to support his idea, but based his hypothesis on the equations used by Einstein and Planck in their discoveries.

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